N'-[(1E)-(2,6-Difluoro-phen-yl)methyl-idene]thio-phene-2-carbohydrazide

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):o315. doi: 10.1107/S160053681105611X. Epub 2012 Jan 11.

Abstract

In the title compound, C(12)H(8)F(2)N(2)OS, the thienyl ring is disordered over two positions, with the S atom of the major component [occupancy = 75.03 (18)%] oriented away from an ortho-F atom of the benzene ring. The mol-ecule is nearly planar, the dihedral angle between the thio-phene and benzene rings being 6.19 (18) (in the major component) or 3.5 (6)° (in the minor component). The azomethine C=N double-bond in the mol-ecule is of an E configuration. In the crystal, mol-ecules are linked by pairs of N-H⋯O hydrogen bonds, generating inversion dimers.