{4-Bromo-2-[(5-chloro-2-oxidophen-yl)imino-methyl]-phenolato-κO,N,O'}(methanol-κO)(methano-lato-κO)-oxidovanadium(V)

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m221-2. doi: 10.1107/S160053681200311X. Epub 2012 Jan 31.

Abstract

The title Schiff base complex, [V(C(13)H(7)BrClNO(2))(CH(3)O)O(CH(3)OH)], features a vanadyl group, a tridentate Schiff base ligand, and coordinated methanol and methano-late ligands. The NO(5) donor set is based on a distorted octa-hedron. Helical supra-molecular chains along [010] are found in the crystal structure mediated by O-H⋯O hydrogen bonds formed between the coordinating methanol mol-ecule and the phenolate O atom of the chloro-benzene residue.