1H-Imidazol-3-ium-4-carboxyl-ate

Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):o134-5. doi: 10.1107/S1600536811052998. Epub 2011 Dec 17.

Abstract

In the title compound, C(4)H(4)N(2)O(2), both imidazole N atoms are protonated and carboxyl-ate group is deprotonated, resulting in a zwitterion. The mol-ecule is essentially planar, with an r.m.s. deviation of 0.012 (1) Å. In the crystal, N-H⋯O hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 3.674 (2) Å] between the imidazole rings link the mol-ecules into a three-dimensional supra-molecular network.