Bis(1,10-phenanthroline-5,6-dione-κN,N')silver(I) 2-hy-droxy-3,5-dinitro-benzoate

Shen-Tang Wang; Guang-Bo Che; Chun-Bo Liu; Xing Wang; Ling Liu

doi:10.1107/S1600536811053785

Bis(1,10-phenanthroline-5,6-dione-κN,N')silver(I) 2-hy-droxy-3,5-dinitro-benzoate

Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):m76. doi: 10.1107/S1600536811053785. Epub 2011 Dec 21.

Authors

Shen-Tang Wang¹, Guang-Bo Che, Chun-Bo Liu, Xing Wang, Ling Liu

Affiliation

¹ School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China.

Abstract

In the cation of the title salt, [Ag(C(12)H(6)N(2)O(2))(2)](C(7)H(3)N(2)O(7)), the Ag(I) atom is coordinated in a distorted tetra-hedral geometry by four N atoms from two 1,10-phenanthroline-5,6-dione ligands, while the 3,5-dinitro-salicylate anion has only a short contact [2.847 (6) Å] between one of its O atoms and the Ag(I) atom. The dihedral angle between the two 1,10-phenanthroline-5,6-dione ligands is 58.4 (1)°. There is an intra-molecular O-H⋯O hydrogen bond in the 3,5-dinitro-salicylate anion.