Synthesis, characterization, and reactivity of a novel μ-η2:η2-diselenidodicopper(II) complex

Jun Matsumoto; Yuji Kajita; Hideki Masuda

doi:10.1021/ic202690e

Synthesis, characterization, and reactivity of a novel μ-η2:η2-diselenidodicopper(II) complex

Inorg Chem. 2012 Feb 6;51(3):1236-8. doi: 10.1021/ic202690e. Epub 2012 Jan 18.

Authors

Jun Matsumoto¹, Yuji Kajita, Hideki Masuda

Affiliation

¹ Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Showa-ku, Nagoya 466-8555, Japan.

PMID: 22257010
DOI: 10.1021/ic202690e

Abstract

The first μ-η(2):η(2)-diselenidodicopper(II) complex has been obtained in the reaction of a copper(I) complex with N,N',N″-tribenzyl-cis,cis-1,3,5-triaminocyclohexane and elemental selenium. The structure and reactivity of the complex is described.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Copper / chemistry*
Molecular Structure
Selenium / chemistry*
Spectrophotometry, Ultraviolet
X-Ray Diffraction

Substances

Copper
Selenium