Enantioselective synthesis of spiro cyclopentane-1,3'-indoles and 2,3,4,9-tetrahydro-1H-carbazoles by iridium-catalyzed allylic dearomatization and stereospecific migration

Angew Chem Int Ed Engl. 2012 Feb 13;51(7):1680-3. doi: 10.1002/anie.201107677. Epub 2012 Jan 5.

Authors

Qing-Feng Wu¹, Chao Zheng, Shu-Li You

Affiliation

¹ State Key Laboratory of Organometallic Chemistry, Shanghai, Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.

PMID: 22223488
DOI: 10.1002/anie.201107677

No abstract available

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Carbazoles / chemical synthesis*
Carbazoles / chemistry
Catalysis
Cyclopentanes / chemical synthesis*
Cyclopentanes / chemistry
Indoles / chemical synthesis*
Indoles / chemistry
Iridium / chemistry*
Molecular Structure
Organometallic Compounds / chemistry*
Spiro Compounds / chemical synthesis*
Spiro Compounds / chemistry
Stereoisomerism

Substances

2,3,4,9-tetrahydro-1H-carbazole
Carbazoles
Cyclopentanes
Indoles
Organometallic Compounds
Spiro Compounds
Iridium