Spin-canting magnetization in an unusual Co4 cluster-based layer compound from a 2,3-dihydroxyquinoxaline ligand

Chen-I Yang; Po-Hsiang Chuang; Gene-Hsiang Lee; Shie-Ming Peng; Kuang-Lieh Lu

doi:10.1021/ic201636g

Spin-canting magnetization in an unusual Co4 cluster-based layer compound from a 2,3-dihydroxyquinoxaline ligand

Inorg Chem. 2012 Jan 16;51(2):757-9. doi: 10.1021/ic201636g. Epub 2011 Dec 22.

Authors

Chen-I Yang¹, Po-Hsiang Chuang, Gene-Hsiang Lee, Shie-Ming Peng, Kuang-Lieh Lu

Affiliation

¹ Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan.

PMID: 22220982
DOI: 10.1021/ic201636g

Abstract

The self-assembly of Co(O(2)CPh)(2) with a 2,3-dihydroxyquinoxaline (H(2)dhq) linker has revealed a new two-dimensional cluster-based compound, [Co(4)(OMe)(2)(O(2)CPh)(2)(dhq)(2)(MeOH)(2)](n), which shows spin-canted magnetization and a definite magnetic hysteresis loop.