Dibromidobis(3,5-dimethyl-1H-pyrazole-κN)cobalt(II)

Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1491. doi: 10.1107/S1600536811039560. Epub 2011 Oct 5.

Abstract

In the mononuclear title complex, [CoBr(2)(C(5)H(8)N(2))(2)], the Co(II) atom is coordinated by two N atoms from two monodentate 3,5-dimethyl-pyrazole ligands and two Br atoms in a highly distorted tetra-hedral geometry. In the crystal, the complex mol-ecules are linked by inter-molecular N-H⋯Br hydrogen bonds into chains along [101]. An intra-molecular N-H⋯Br hydrogen bond is also present.