Undeca-carbonyl-μ(2)-methane-thiol-ato-μ(2)-[(pyridin-2-yl)methane-thiol-ato]-μ(4)-sulfido-tetra-iron(II)(2 Fe-Fe)

Yao-Cheng Shi; Liang Lai; Wen-Bin Shen; Li-Min Yuan

doi:10.1107/S1600536811047751

Undeca-carbonyl-μ(2)-methane-thiol-ato-μ(2)-[(pyridin-2-yl)methane-thiol-ato]-μ(4)-sulfido-tetra-iron(II)(2 Fe-Fe)

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1763. doi: 10.1107/S1600536811047751. Epub 2011 Nov 16.

Authors

Yao-Cheng Shi, Liang Lai, Wen-Bin Shen, Li-Min Yuan

Abstract

The title compound, [Fe(4)(C(6)H(6)NS)(CH(3)S)S(CO)(11)], com-prises two butterfly-shaped sub-cluster cores, Fe(2)S(2)N and Fe(2)S(2), joined together by a spiro-type μ(4)-S atom. The (pyridin-2-yl)methane-thiol-ate ligand is attached to the Fe(2)(CO)(5) unit in a μ-κN:κ(2)S mode, and the methane-thiol-ate ligand is coordinated to the Fe(2)(CO)(6) unit in a μ-κ(2)S fashion.