[η-1,3-Bis(trimethyl-sil-yl)cyclo-penta-dien-yl]dichlorido[η-(trimethyl-sil-yl)cyclo-penta-dien-yl]titanium(IV)

Franc Perdih

doi:10.1107/S1600536811046228

[η-1,3-Bis(trimethyl-sil-yl)cyclo-penta-dien-yl]dichlorido[η-(trimethyl-sil-yl)cyclo-penta-dien-yl]titanium(IV)

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1693. doi: 10.1107/S1600536811046228. Epub 2011 Nov 5.

Author

Franc Perdih¹

Affiliation

¹ Faculty of Chemistry and Chemical Technology, University of Ljubljana, Aškerčeva 5, PO Box 537, SI-1000 Ljubljana, Slovenia, and CO EN-FIST, Dunajska 156, SI-1000 Ljubljana, Slovenia.

Abstract

In the title compound, [Ti(C(8)H(13)Si)(C(11)H(21)Si(2))Cl(2)], the Ti(IV) atom is bonded to two Cl atoms, one 1,3-bis-(trimethyl-sil-yl)cyclo-penta-dienyl (Si(2)Cp) and one (trimethyl-sil-yl)cyclo-penta-dienyl ring (SiCp). The Si(2)Cp centroid-titanium distance is 2.0763 (10) Å and the SiCp centroid-titanium distance is 2.0793 (10) Å. The angle subtended at the Ti atom by the centroids of both cyclo-penta-dienyl rings is 131.22 (4)° and the Cl-Ti-Cl angle is 94.14 (2)°.