2-Chloro-methyl-1-methyl-1,3-benzimidazole

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2104. doi: 10.1107/S1600536811028376. Epub 2011 Jul 23.

Abstract

The title compound, C(9)H(9)ClN(2), was prepared from the reaction of N-methyl-benzene-1,2-diamine and 2-chloro-acetic acid in boiling 6 M hydro-chloric acid. The benzimidazole unit is approximately planar, the largest deviation from the mean plane being 0.008 (1) Å. The Cl atom is displaced by 1.667 (2) Å from this plane. The methyl group is statistically disordered with equal occupancy.