{μ-6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diyl-bis(nitrilo-methanylyl-idene)]diphenolato-1κO,O,O,O;2κO,N,N',O}(methanol-1κO)(tetra-fluoridoborato-1κF,F')-2-copper(II)-1-sodium

Ting Gao; Yu Yang; Po Gao; Ju-Wen Zhang; Jing-Lin Yang

doi:10.1107/S160053681102842X

{μ-6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diyl-bis(nitrilo-methanylyl-idene)]diphenolato-1κO,O,O,O;2κO,N,N',O}(methanol-1κO)(tetra-fluoridoborato-1κF,F')-2-copper(II)-1-sodium

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1127. doi: 10.1107/S160053681102842X. Epub 2011 Jul 23.

Authors

Ting Gao¹, Yu Yang, Po Gao, Ju-Wen Zhang, Jing-Lin Yang

Affiliation

¹ School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.

Abstract

In the dinuclear salen-type title complex, [CuNa(BF(4))(C(18)H(18)N(2)O(4))(CH(3)OH)], the Cu(II) atom is chelated by two O atoms and two N atoms of the deprotonated Schiff base in a square-planar geometry. The Na atom is seven-coordinate as it is linked to four O atoms of the same Schiff base ligand, one O atom of the methanol and two tetra-fluorido-borate F atoms. The remaining two F atoms of the anion are disordered over two sites in a 0.598 (18):0.402 (18) ratio.