Stochastic state-space temperature regulation of biochar production. Part II: Application to manure processing via pyrolysis

J Sci Food Agric. 2012 Feb;92(3):490-5. doi: 10.1002/jsfa.4617. Epub 2011 Oct 10.

Abstract

Background: State-of-the-art control systems that can guarantee the pyrolytic exposure temperature are needed in the production of designer biochars. These designer biochars will have tailored characteristics that can offer improvement of specific soil properties such as water-holding capacity and cation exchange capacity.

Results: A novel stochastic state-space temperature regulator was developed for the batch production of biochar that accurately matched the pyrolytic exposure temperature to a defined temperature input schedule. This system was evaluated by processing triplicate swine manure biochars at two temperatures, 350 and 700 °C. The results revealed a low coefficient of variation (CV) in their composition and near-similar ¹³C nuclear magnetic resonance structure as well as thermal degradation patterns. When pyrolysing at 350 °C, the stochastic state-space regulator generated a biochar with lower CV in ultimate (i.e. CHNS) compositional analysis than the original feedstock.

Conclusion: This state-space controller had the ability to pyrolyse a feedstock and generate a consistent biochar with similar structural properties and consistent compositional characteristics.

Keywords: char; process control; pyrolysis; waste minimization; waste treatment.

Publication types

  • Comparative Study
  • Evaluation Study

MeSH terms

  • Animal Husbandry / economics
  • Animals
  • Charcoal / analysis
  • Charcoal / chemistry*
  • Charcoal / economics
  • Chemical Phenomena
  • Fertilizers / analysis*
  • Fertilizers / economics
  • Heating / instrumentation
  • Hot Temperature
  • Industrial Waste / analysis
  • Industrial Waste / economics
  • Kinetics
  • Manure / analysis*
  • Nitrogen / chemistry
  • Quality Control
  • Reproducibility of Results
  • Stochastic Processes
  • Sus scrofa
  • United States

Substances

  • Fertilizers
  • Industrial Waste
  • Manure
  • biochar
  • Charcoal
  • Nitrogen