Palladium-catalyzed oxidative carbocyclization/arylation of enallenes

Tuo Jiang; Andreas K Å Persson; Jan-E Bäckvall

doi:10.1021/ol202451f

Palladium-catalyzed oxidative carbocyclization/arylation of enallenes

Org Lett. 2011 Nov 4;13(21):5838-41. doi: 10.1021/ol202451f. Epub 2011 Oct 3.

Authors

Tuo Jiang¹, Andreas K Å Persson, Jan-E Bäckvall

Affiliation

¹ Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-10691, Stockholm, Sweden.

PMID: 21967017
DOI: 10.1021/ol202451f

Abstract

A stereoselective palladium-catalyzed oxidative carbocyclization/arylation of enallenes is described. The reaction shows wide tolerance toward highly functionalized arylboronic acids and results in a cis addition of two carbon moieties to an olefin in good to excellent yields.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Alkenes / chemistry*
Catalysis
Cyclization
Molecular Structure
Oxidation-Reduction
Palladium / chemistry*
Stereoisomerism

Substances

Alkenes
Palladium