The use of fluoride as a leaving group: SN2' displacement of a C-F bond on 3,3-difluoropropenes with organolithium reagents to give direct access to monofluoroalkenes

Angew Chem Int Ed Engl. 2011 Nov 18;50(47):11112-6. doi: 10.1002/anie.201105138. Epub 2011 Sep 28.
No abstract available

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkenes* / chemical synthesis
  • Alkenes* / chemistry
  • Allyl Compounds / chemistry*
  • Fluorides / chemistry*
  • Hydrocarbons, Fluorinated* / chemical synthesis
  • Hydrocarbons, Fluorinated* / chemistry
  • Lithium / chemistry*
  • Molecular Structure
  • Organometallic Compounds / chemistry*

Substances

  • 3,3-difluoropropene
  • Alkenes
  • Allyl Compounds
  • Hydrocarbons, Fluorinated
  • Organometallic Compounds
  • n-butyllithium
  • Lithium
  • Fluorides