Acetophenone hydrogenation over a Pd catalyst in the presence of H2O and CO2

Chem Commun (Camb). 2011 Nov 7;47(41):11546-8. doi: 10.1039/c1cc13130c. Epub 2011 Sep 26.

Abstract

The addition of carbon dioxide and water enhances acetophenone hydrogenation activity over an activated carbon-supported palladium catalyst, and 1-phenylethanol can be easily recovered without distillation and neutralization. Two liquid phases (water and acetophenone) are indispensable for enhancement of the hydrogenation rate.