Abstract
Newly developed oxo-tethered Ru amido complexes (R,R)-1 and their HCl adducts (R,R)-2 exhibited excellent catalytic performance for both asymmetric transfer hydrogenation and the hydrogenation of ketonic substrates under neutral conditions without any cocatalysts to give chiral secondary alcohols with high levels of enantioselectivity.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alcohols / chemical synthesis*
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Alcohols / chemistry
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Amides / chemistry*
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Catalysis
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Hydrogen / chemistry*
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Hydrogenation
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Ketones / chemistry
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Lactones / chemistry
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemical synthesis
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Organometallic Compounds / chemistry*
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Ruthenium / chemistry*
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Stereoisomerism
Substances
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Alcohols
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Amides
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Ketones
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Lactones
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Organometallic Compounds
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Ruthenium
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Hydrogen