Abstract
A new heterometallic electroactive compound having the ferrocenyl moiety attached to the platinum atom through an amidine functionality has been prepared via Pt(II)-mediated nucleophilic addition of β-aminoethylferrocene to a benzonitrile ligand. This neutral receptor shows remarkable electrochemical anion-sensing redox response to H(2)PO(4)(-).
This journal is © The Royal Society of Chemistry 2011
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Amidines / chemistry*
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Catalysis
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Chemistry Techniques, Analytical / instrumentation*
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Ferrous Compounds / chemistry*
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Ligands
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Nitriles / chemistry*
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Organometallic Compounds / chemistry
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Oxidation-Reduction
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Phosphates / analysis*
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Phosphates / chemistry
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Platinum / chemistry*
Substances
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Amidines
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Ferrous Compounds
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Ligands
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Nitriles
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Organometallic Compounds
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Phosphates
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ethylferrocene
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Platinum
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benzonitrile