Methyl 2-benzyl-4-hy-droxy-1,1-dioxo-1,2,3,4-tetra-hydro-1λ,2-benzothia-zine-3-carboxyl-ate

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):o1588-9. doi: 10.1107/S1600536811020289. Epub 2011 Jun 4.

Abstract

In the title compound, C(17)H(15)NO(5)S, the benzene ring of the fused-ring system is twisted by 11.67 (6)° with respect to the thia-zine ring. The atoms of the four-atom methyl ester group and the phenyl ring of the benzyl unit are inclined at 16.50 (7) and 44.52 (3)° with respect to the thia-zine ring. An intra-molecular O-H⋯O hydrogen bond gives rise to a six-membered S(6) ring motif. In the crystal, mol-ecules are extended through a C-H⋯O inter-action along the a axis. C-H⋯π inter-actions are also observed.