Poly[[(1,10-phenanthroline-κN,N')zinc]-μ-2,5-bis-(all-yloxy)terephthalato-κO:O]

Ruofei Hu; Yuanying Hu; Qingzeng Zhu

doi:10.1107/S1600536811022392

Poly[[(1,10-phenanthroline-κN,N')zinc]-μ-2,5-bis-(all-yloxy)terephthalato-κO:O]

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m936. doi: 10.1107/S1600536811022392. Epub 2011 Jun 18.

Authors

Ruofei Hu¹, Yuanying Hu, Qingzeng Zhu

Affiliation

¹ School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, People's Republic of China.

Abstract

The title compound, [Zn(C(14)H(12)O(6))(C(12)H(8)N(2))](n), is a coordination polymer forming one-dimensional infinite zigzag chains along [10[Formula: see text]] by inter-connection of Zn(II) atoms by 2,5-bis-(all-yl-oxy)-terephthalate anions via the carboxyl-ate groups. The Zn(II) atom is located on a twofold axis and is in a distorted tetra-hedral coordination formed by the two carboxyl-ate O atoms [Zn-O = 1.9647 (12) Å] and two phenanthroline N atoms [Zn-N = 2.0949 (14) Å].