trans-Diaqua-bis-(1H-imidazole-4-carboxyl-ato-κN,O)nickel(II)

Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m865. doi: 10.1107/S1600536811018824. Epub 2011 Jun 11.

Abstract

In the title complex, [Ni(C(4)H(3)N(2)O(2))(2)(H(2)O)(2)], the Ni(II) ion is located on an inversion center and shows a distorted octa-hedral geometry, defined by two N,O-bidentate 1H-imidazole-4-carboxyl-ate ligands in the equatorial plane and two water mol-ecules in the axial positions. Inter-molecular N-H⋯O hydrogen bonds link the complex mol-ecules into layers parallel to (10[Formula: see text]), which are further linked into a three-dimensional supra-molecular network through O-H⋯O hydrogen bonds.