Construction of polyoxometalate-based inorganic-organic compounds using silver(I) double helicates as secondary building blocks

Inorg Chem. 2011 Sep 5;50(17):7907-9. doi: 10.1021/ic200159w. Epub 2011 Aug 9.

Abstract

Two polyoxometalate-based silver(I) compounds including a three-dimensional porous crystalline array and a double-helicate bisupporting cluster were achieved using metal-organic helicates and Keggin [PMo(12)O(40)](3-) as secondary building blocks.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Models, Molecular
  • Organometallic Compounds / chemical synthesis*
  • Organometallic Compounds / chemistry
  • Porosity
  • Silver / chemistry*
  • Surface Properties
  • Tungsten Compounds / chemistry*

Substances

  • Organometallic Compounds
  • Tungsten Compounds
  • polyoxometalate I
  • Silver