Piezoresistivity and electro-thermomechanical degradation of a conducting layer of nanoparticles integrated at the liquid crystal elastomer surface

Nanotechnology. 2008 Apr 16;19(15):155501. doi: 10.1088/0957-4484/19/15/155501. Epub 2008 Mar 11.

Abstract

When a liquid crystal elastomer (LCE) is reprocessed with conducting nanosized particles a conducting layer can be formed at the LCE surfaces. Here, two different LCE materials and two different conducting carbon particles were used. These four reprocessed LCEs were investigated when subject to a thermal phase transition and mechanical extension. Here it is shown that the resistance change with strain ('piezoresistivity') for these reprocessed LCEs can be described through lattice percolation and geometrical changes in the LCE shape. The mechanisms and rate of degradation are also described for the conducting layer as a function of the number of electro-thermomechanical strain cycles performed.