Novel octatungstate-supported tricarbonyl metal derivatives: {[H2W8O30][M(CO)3]2}8- (M = Mn(I) and Re(I))

Dalton Trans. 2011 Sep 7;40(33):8298-300. doi: 10.1039/c1dt11042j. Epub 2011 Jul 21.

Abstract

Three novel octatungstate-supported tricarbonyl metal derivatives have been synthesized and characterized, which represent the first examples of isopolyoxotungstates-supported carbonyl metal compounds.