1,1'-[(1E,11E)-5,8-Dioxa-2,11-diazo-nia-dodeca-1,11-diene-1,12-di-yl]dinaph-thal-en-2-olate

Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1074. doi: 10.1107/S1600536811012219. Epub 2011 Apr 7.

Abstract

The title compound, C(28)H(28)N(2)O(4), crystallizes in a zwitterionic form with deprotonated naphthol hy-droxy groups and protonated imine N atoms. The asymmetric unit contains one half-mol-ecule located on a twofold rotation axis. Intra-molecular N-H⋯O hydrogen bonds occur and the two bicyclic ring systems form a dihedral angle of 64.2 (1)°. In the crystal, weak inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into layers parallel to the bc plane.