Poly[[[silver(I)-μ-1,4-bis-[(imidazol-1-yl)meth-yl]benzene-κN:N-silver(I)-μ-1,4-bis-[(imidazol-1-yl)meth-yl]benzene-κN:N] 4,4'-diazenediyldibenzoate] dihydrate]

Qian Qiao; Mei Tian; Da-Yong Liu; Shu-Jiang Wang

doi:10.1107/S1600536811008816

Poly[[[silver(I)-μ-1,4-bis-[(imidazol-1-yl)meth-yl]benzene-κN:N-silver(I)-μ-1,4-bis-[(imidazol-1-yl)meth-yl]benzene-κN:N] 4,4'-diazenediyldibenzoate] dihydrate]

Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m473. doi: 10.1107/S1600536811008816. Epub 2011 Mar 23.

Authors

Qian Qiao¹, Mei Tian, Da-Yong Liu, Shu-Jiang Wang

Affiliation

¹ College of Chemical Engineering, Changchun University of Technology, Changchun 130012, People's Republic of China.

Abstract

In the title compound, [Ag(2)(C(14)H(14)N(4))(2)](C(14)H(8)N(2)O(4))·2H(2)O, each of the two unique Ag(+) ions is two-coordinated by two N atoms from two different 1,4-bis-[(imidazol-1-yl)meth-yl]benzene ligands in an almost linear fashion [N-Ag-N = 170.34 (10) and 160.25 (10)°]. The 4,4'-diazenediyldibenzoate anions do not coordinate to Ag. O-H⋯O hydrogen bonds stabilize the crystal structure.