Supernovae, neutrinos and the chirality of amino acids

Int J Mol Sci. 2011;12(6):3432-44. doi: 10.3390/ijms12063432. Epub 2011 May 31.

Abstract

A mechanism for creating an enantioenrichment in the amino acids, the building blocks of the proteins, that involves global selection of one handedness by interactions between the amino acids and neutrinos from core-collapse supernovae is defined. The chiral selection involves the dependence of the interaction cross sections on the orientations of the spins of the neutrinos and the (14)N nuclei in the amino acids, or in precursor molecules, which in turn couple to the molecular chirality. It also requires an asymmetric distribution of neutrinos emitted from the supernova. The subsequent chemical evolution and galactic mixing would ultimately populate the Galaxy with the selected species. The resulting amino acids could either be the source thereof on Earth, or could have triggered the chirality that was ultimately achieved for Earth's proteinaceous amino acids.

Keywords: amino acids; chirality; molecular clouds; origin of life; supernova neutrinos.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acids / chemistry*
  • Evolution, Chemical
  • Magnetic Fields
  • Neutrons
  • Nitrogen / chemistry
  • Origin of Life
  • Stereoisomerism

Substances

  • Amino Acids
  • Nitrogen