Manganese(III)-mediated phosphinoyl radical reactions for stereoselective synthesis of phosphinoylated tetrahydronaphthalenes

Xiang-Qiang Pan; Lu Wang; Jian-Ping Zou; Wei Zhang

doi:10.1039/c1cc12343b

Manganese(III)-mediated phosphinoyl radical reactions for stereoselective synthesis of phosphinoylated tetrahydronaphthalenes

Chem Commun (Camb). 2011 Jul 21;47(27):7875-7. doi: 10.1039/c1cc12343b. Epub 2011 Jun 1.

Authors

Xiang-Qiang Pan¹, Lu Wang, Jian-Ping Zou, Wei Zhang

Affiliation

¹ College of Chemistry and Chemical Engineering, Suzhou University, 199 Renai Street, Suzhou, Jiangsu 215123, China.

PMID: 21633750
DOI: 10.1039/c1cc12343b

Abstract

Reactions of diphenylphosphinoyl radicals with 5-aryl-2-pentenoates or β-phenylethylene styrenes generate trans-substituted tetrahydronaphthalenes through a cascade reaction sequence.