Squaraine [2]catenanes: synthesis, structure and molecular dynamics

Chem Commun (Camb). 2011 Jul 7;47(25):7188-90. doi: 10.1039/c1cc10946d. Epub 2011 May 19.

Abstract

Three squaraine [2]catenanes are synthesized and found to have bright, deep-red fluorescence and high chemical stability. The interlocked molecules undergo two large-amplitude dynamic processes, twisting of the squaraine macrocycle and skipping over the partner tetralactam.