{N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N'',N'''}bis-(thio-cyanato-κN)manganese(II)

Fu-Ming Wang

doi:10.1107/S1600536810021550

{N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N'',N'''}bis-(thio-cyanato-κN)manganese(II)

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m776. doi: 10.1107/S1600536810021550.

Author

Fu-Ming Wang¹

Affiliation

¹ Department of Chemistry, Dezhou University, Dezhou Shandong 253023, People's Republic of China.

Abstract

The mol-ecule of the title compound, [Mn(NCS)(2)(C(16)H(18)N(4))], has crystallographic twofold rotation symmetry, with the Mn(II) atom lying on the rotation axis. The Mn(II) atom is six-coordinated by four N atoms of the Schiff base ligand and by two N atoms of two thio-cyanate ligands, forming a distorted octa-hedral geometry.