In the title compound, C(27)H(24)O(14), also known as 2,3-di-acetoxy-5-[(2RS,3RS)-3,5,7-triacetoxy-4-oxochromen-2-yl]phenyl acetate, the heterocyclic ring adopts a distorted half-chair conformation, with two C atoms displaced by 0.1775 (16) and -0.5950 (16) Å from the mean plane of the other four atoms. The dihedral angle between the aromatic rings is 57.81 (8)°. In the crystal, the mol-ecules inter-act by C-H⋯O bonds, aromatic π-π stacking [centroid-centroid separation = 3.6206 (9) Å] and C-H⋯π inter-actions.