The title structure, [Au(2)Cl(2)(C(25)H(22)As(2))], consists of discrete mol-ecules disposed about a crystallographic twofold axis. The Au atom exhibits a nearly linear coordination by As and Cl atoms. Au⋯Au inter-actions [3.4285Å(4) Å] and a weak intermolecular C-H⋯Cl hydrogen bond are present.