Bis(5-chloro-quinolin-8-olato-κN,O)bis-(propan-2-olato-κO)titanium(IV)

Yousef Fazaeli; Ezzatollah Najafi; Mostafa M Amini; Seik Weng Ng

doi:10.1107/S1600536809004383

Bis(5-chloro-quinolin-8-olato-κN,O)bis-(propan-2-olato-κO)titanium(IV)

Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 13;65(Pt 3):m271. doi: 10.1107/S1600536809004383.

Authors

Yousef Fazaeli, Ezzatollah Najafi, Mostafa M Amini, Seik Weng Ng

Abstract

The Ti(IV) atom in the title compound, [Ti(C(9)H(5)ClNO)(2)(C(3)H(7)O)(2)], is chelated by the substituted quinolin-8-olate anions in a distorted octa-hedral geometry. The N-donor atoms are in a cis alignment as are the O atoms of the propan-2-olate groups; the O atoms of the quinolin-8-olate groups are trans to each other. One C atom of one propan-2-olate group is disordered over two positions with occupancies of 0.733 (8):0.267 (8).