Dichlorido{[2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene-κN,P}platinum(II) dichloro-methane hemisolvate

Yu Xie; Ya Wei; Jin-Gang Hu; Jin-Sheng Zhao; Feng-Xing Jiang

doi:10.1107/S1600536808043493

Dichlorido{[2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene-κN,P}platinum(II) dichloro-methane hemisolvate

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 8;65(Pt 2):m138. doi: 10.1107/S1600536808043493.

Authors

Yu Xie, Ya Wei, Jin-Gang Hu, Jin-Sheng Zhao, Feng-Xing Jiang

Abstract

In the title compound, [FePt(C(5)H(5))(C(24)H(19)NP)Cl(2)]·0.5CH(2)Cl(2), the Pt(II) atom adopts a distorted square-planar geometry defined by one P atom and one N atom from the bidentate [2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferro-cene ligand and two Cl atoms. Two disordered dichloro-methane solvent mol-ecules are each 0.25-occupied on a twofold rotation axis.