catena-Poly[[trimethyl-tin(IV)]-μ-2-(3-thien-yl)acetato]

Minglei Yang; Handong Yin; Liyuan Wen; Wenkuan Li; Daqi Wang

doi:10.1107/S1600536808040762

catena-Poly[[trimethyl-tin(IV)]-μ-2-(3-thien-yl)acetato]

Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 10;65(Pt 1):m35. doi: 10.1107/S1600536808040762.

Authors

Minglei Yang¹, Handong Yin, Liyuan Wen, Wenkuan Li, Daqi Wang

Affiliation

¹ College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

Abstract

The title compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), forms an infinite chain structure parallel to [100]. There are two mol-ecules of the complex in the asymmetric unit. The geometry of the Sn atoms in both mol-ecules is distorted trigonal-bipyramidal. The S and C atoms of the thio-phene rings in both mol-ecules are disordered over two sites with site-occupancy factors 0.799 (9)/0.201 (9) and 0.618 (7)/0.382 (7), respectively.