Di-μ-chlorido-bis-{bis-[3,5-dimethyl-pyrazol-1-yl-κN)methane]iron(II)} bis-[tetra-chloridoferrate(III)]

Hongying Xia; Yuelong Liu

doi:10.1107/S1600536808035253

Di-μ-chlorido-bis-{bis-[3,5-dimethyl-pyrazol-1-yl-κN)methane]iron(II)} bis-[tetra-chloridoferrate(III)]

Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 8;64(Pt 12):m1504. doi: 10.1107/S1600536808035253.

Authors

Hongying Xia¹, Yuelong Liu

Affiliation

¹ College of Chemistry and Chemical Engineering, Jiangxi Science and Technology Normal University, Nanchang 330013, People's Republic of China.

Abstract

In the title complex, [Fe(2)Cl(2)(C(11)H(16)N(4))(4)][FeCl(4)](2), the asymmetric unit is composed of one and a half units of [Fe(bdmpm)(2)Cl](2)(FeCl(4))(2)(bdmpm = bis(bis(3,5-dimethyl-pyrazol-1-yl)methane). The three independent Fe(II) atom have a distorted octa-hedral coordination geometry comprising two bridging chloride anions and four N atoms from two bis-(3,5-dimethyl-pyrazol-1-yl)methane ligands. The Fe(III) atom has a tetra-hedral coordination geometry comprising four chloride anions.