Di-μ-ethano-lato-bis-[diethano-lato(2-methyl-quinolin-8-olato)titanium(IV)]

Yousef Fazaeli; Ezzatollah Najafi; Mostafa M Amini; Hamid Reza Khavasi

doi:10.1107/S1600536809045796

Di-μ-ethano-lato-bis-[diethano-lato(2-methyl-quinolin-8-olato)titanium(IV)]

Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 7;65(Pt 12):m1531. doi: 10.1107/S1600536809045796.

Authors

Yousef Fazaeli¹, Ezzatollah Najafi, Mostafa M Amini, Hamid Reza Khavasi

Affiliation

¹ Department of Chemistry, Shahid Beheshti University, G. C., Evin, Tehran 1983963113, Iran.

Abstract

In the centrosymmetric dinuclear title compound, [Ti(2)(C(10)H(8)NO)(2)(C(2)H(5)O)(6)], the Ti atom is bonded to an N,O-bidentate quinolin-8-olate ligand, two terminal ethano-late anions and two bridging ethano-late anions in a distorted TiNO(5) octa-hedral geometry. An intra-molecular C-H⋯O hydrogen bond occurs; in the crystal, inter-molecular C-H⋯O inter-actions help to establish the packing.