[N'-(3-Meth-oxy-2-oxidobenzyl-idene-κO)benzohydrazidato-κN',O]tris-(pyridine-κN)cobalt(III) perchlorate

Gui-Miao Yu; Xiu-Yun Yang; Yuan Wang; Ya-Juan Xiao; Yun-Hui Li

doi:10.1107/S1600536811004715

[N'-(3-Meth-oxy-2-oxidobenzyl-idene-κO)benzohydrazidato-κN',O]tris-(pyridine-κN)cobalt(III) perchlorate

Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 12;67(Pt 3):m329. doi: 10.1107/S1600536811004715.

Authors

Gui-Miao Yu¹, Xiu-Yun Yang, Yuan Wang, Ya-Juan Xiao, Yun-Hui Li

Affiliation

¹ School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, People's Republic of China.

Abstract

In the mononuclear title compound, [Co(III)(C(15)H(12)N(2)O(3))(C(5)H(5)N)(3)]ClO(4), the Co(III) ion is coordinated by three pyridine mol-ecules and one N'-(3-meth-oxy-2-oxidobenzyl-idene)benzohydrazidate Schiff base ligand in an O,N,O'-tridentate manner. The Co(III) ion adopts a distorted CoN(4)O(2) octa-hedral coordination environment.