Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds

Torsten Beweries; Sven Hansen; Monty Kessler; Marcus Klahn; Uwe Rosenthal

doi:10.1039/c1dt10366k

Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds

Dalton Trans. 2011 Aug 14;40(30):7689-92. doi: 10.1039/c1dt10366k. Epub 2011 Apr 21.

Authors

Torsten Beweries¹, Sven Hansen, Monty Kessler, Marcus Klahn, Uwe Rosenthal

Affiliation

¹ Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059, Rostock, Germany.

PMID: 21512699
DOI: 10.1039/c1dt10366k

Abstract

Dehydrogenation of Me(2)NH·BH(3) (1) by group 4 metallocene alkyne complexes of the type Cp(2)M(L)(η(2)-Me(3)SiC(2)SiMe(3)) [Cp = η(5)-cyclopentadienyl; M = Ti, no L (2Ti); M = Zr, L = pyridine (2Zr)] and group 4 metal amido complexes of the type M(NMe(2))(4) [M = Ti (8Ti), Zr (8Zr)] is presented.