Host-guest chemistry at interface for photoswitchable bioelectrocatalysis

Chem Commun (Camb). 2011 Jun 7;47(21):5994-6. doi: 10.1039/c1cc11289a. Epub 2011 Apr 21.

Abstract

Photoswitchable bioelectrocatalysis of glucose with glucose oxidase in an "On-Off" state is fabricated from host-guest chemistry at an interface by using the photocontrolled reversible immobilization and detachment of ferrocene-labeled redox-polymer as mediator.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Biocatalysis
  • Biosensing Techniques
  • Electrochemical Techniques
  • Electrodes
  • Ferrous Compounds / chemistry
  • Glucose / metabolism*
  • Glucose Oxidase / chemistry
  • Glucose Oxidase / metabolism*
  • Immobilized Proteins / chemistry
  • Immobilized Proteins / metabolism
  • Light*
  • Metallocenes
  • Oxidation-Reduction
  • Polymers / chemistry
  • beta-Cyclodextrins / chemistry

Substances

  • Ferrous Compounds
  • Immobilized Proteins
  • Metallocenes
  • Polymers
  • beta-Cyclodextrins
  • Glucose Oxidase
  • Glucose
  • ferrocene