A new approach towards tetrahedral imidazolate frameworks for high and selective CO2 uptake

Chem Commun (Camb). 2011 May 28;47(20):5828-30. doi: 10.1039/c1cc10829h. Epub 2011 Apr 12.

Abstract

Successful development of a new synthetic approach towards tetrahedral imidazolate frameworks (TIFs) via combining an auxiliary uninegative linker into the zinc-imidazolate tetrahedral assembly leads to new TIF materials (TIF-A1 to TIF-A3) with distinct structural topologies and high CO(2) uptake capacity.