We simulate the effect of the chaining direction of ellipsoidal particles of polar molecule dominated electrorheological (PM-ER) fluids using commercially available COMSOL Multiphysics® software for the distribution of electric field and the total electrostatic energy. It is proved that adding ferroelectric materials to the channels parallel to the short axis would make the short axis parallel to the field direction when the ellipsoidal particles are chained under an electric field. According to our simulation, while the concentration of the channels stays constant, the greater the dielectric constant of the inserted material, the stronger the maximum local electric field will be.