Abstract
A new three-dimensional metal-organic framework (MOF) containing Fe(II) and Ag(I) ions and 2-pyrazinecarboxylic acid (pcaH) was synthesized, and its magnetic and catalytic properties were studied. The MOF has a big window size of 12.1 × 12.0 Å, with 23.8% solvent-accessible space, and shows size selectivity toward Lewis acid catalysis.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Carboxylic Acids / chemistry*
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Crystallography, X-Ray
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Iron / chemistry*
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemical synthesis*
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Organometallic Compounds / chemistry*
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Silver / chemistry*
Substances
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Carboxylic Acids
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Organometallic Compounds
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Silver
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Iron