Mesoporous rare earth fluoride nanocrystals and their photoluminescence properties

J Colloid Interface Sci. 2011 May 1;357(1):116-20. doi: 10.1016/j.jcis.2011.01.100. Epub 2011 Feb 3.

Abstract

YF(3) and YF(3):Eu(3+) mesoporous hexagonal nanocrystals were successfully synthesized via a simple hydrothermal process based on the in situ assembly of the as-synthesized YF(3) and YF(3):Eu(3+) nanoparticles. The well defined mesoporous nanostructures are formed by phenanthroline assisted assembly of ∼20 nm nanoparticles, and 2-4 nm pores are contained as indicated by N(2) adsorption-desorption studies. The obtained YF(3):Eu(3+) mesoporous hexagonal nanoplates show a significant photoluminescence intensity enhancement compared with other shaped YF(3):Eu(3+) nanocrystals.