Abstract
The first and highly efficient total synthesis of (-)-brevisin has been achieved. The title compound was synthesized in only 29 steps (longest linear sequence) from commercially available starting materials. The synthesis provided over 70 mg of a marine polycyclic ether compound.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
MeSH terms
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Dinoflagellida / chemistry
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Ethers, Cyclic / chemical synthesis*
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Ethers, Cyclic / chemistry
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Marine Biology
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Molecular Structure
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Polycyclic Compounds / chemical synthesis*
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Polycyclic Compounds / chemistry
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Stereoisomerism
Substances
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Ethers, Cyclic
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Polycyclic Compounds
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brevisin