Diazido-bis(2,2'-biimidazole)iron(II)

Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 25;64(Pt 7):m956. doi: 10.1107/S1600536808018539.

Abstract

In the title compound, [Fe(N(3))(2)(C(6)H(6)N(4))(2)], the Fe atom is bonded to two azide ions located in axial positions and to two equatorially positioned bidentate biimidazole ligands, forming a slightly distorterd octa-hedron. The non-H atoms of the equatorial plane are coplanar, with a mean deviation of 0.0355 (2) Å. The Fe(II) cation lies on an inversion centre. Thus, the asymmetric unit comprises one half-mol-ecule.

Publication types

  • Retracted Publication