Di-μ-chlorido-bis-[bis-(η-cyclo-octene)iridium(I)]

Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 29;64(Pt 4):m579-80. doi: 10.1107/S1600536808007216.

Abstract

The title complex, [Ir(2)(μ-Cl)(2)(C(8)H(14))(4)], has a dinuclear structure with bridging Cl atoms, a hinge angle of 179.44 (7)° between the two IrCl(2) planes, and an Ir⋯Ir distance of 3.7254 (3) Å. Regarding the coordinating C=C bonds as occupying a single coordination site each, the geometry around each Ir atom is square-planar.