catena-Poly[[bis-(1H-benzimidazole-κN)palladium(II)]-μ-benzene-1,4-dicarboxyl-ato-κO:O]

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):m133. doi: 10.1107/S1600536807065051.

Abstract

In the title compound, [Pd(C(8)H(4)O(4))(C(7)H(6)N(2))(2)](n), the Pd atom is tetra-coordinated by two carboxyl-ate O atoms from two benzene-1,4-dicarboxyl-ate (bdc) dianions and two N atoms from two benzimidazole ligands, resulting in a slightly distorted tetra-hedral PdO(2)N(2) geometry. The bdc ligand acts as a bridge, linking the Pd atoms into a chain. Inter-chain N-H⋯O hydrogen bonds help to stabilize the crystal structure.

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  • Retracted Publication