Pyromellitic diimide dilithium salt was selected to complete our database on redox-active polyketones with a N-cyclic structure. Although never reported to date, such a lithiated salt was readily synthesized making its electrochemical evaluation in a Li battery possible. Preliminary data show that this novel material reversibly inserts two Li per formula unit at a relatively low potential giving a stable capacity value of 200 mAh g(-1).