Co nanoparticles inserted into a porous carbon amorphous matrix: the role of cooling field and temperature on the exchange bias effect

Phys Chem Chem Phys. 2011 Jan 21;13(3):927-32. doi: 10.1039/c0cp00396d. Epub 2010 Nov 29.

Abstract

We report unusual cooling field dependence of the exchange bias in oxide-coated cobalt nanoparticles embedded within the nanopores of a carbon matrix. The size-distribution of the nanoparticles and the exchange bias coupling observed up to about 200 K between the Co-oxide shell (∼3-4 nm) and the ferromagnetic Co-cores (∼4-6 nm) are the key to understand the magnetic properties of this system. The estimated values of the effective anisotropy constant and saturation magnetization obtained from the fit of the zero-field cooling and field cooling magnetization vs. temperature curves agree quite well with those of the bulk fcc-Co.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbon / chemistry*
  • Cobalt / chemistry*
  • Magnetics
  • Metal Nanoparticles / chemistry*
  • Metal Nanoparticles / ultrastructure
  • Oxides / chemistry*
  • Porosity
  • Temperature

Substances

  • Oxides
  • Cobalt
  • Carbon
  • cobalt oxide